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- Drummond, Michael J., et al. Show all 5 Authors
- Journal of the American Chemical Society 2019 v.141 no.16 pp. 6639-6650
- active sites; dissociation; enzymes; hydrogen bonding; hydroxylation; iron; ligands; models; oxygen
- ... The characterization of high-valent iron centers in enzymes has been aided by synthetic model systems that mimic their reactivity or structural and spectral features. For example, the cleavage of dioxygen often produces an iron(IV)-oxo that has been characterized in a number of enzymatic and synthetic systems. In non-heme 2-oxogluterate dependent (iron-2OG) enzymes, the ferryl species abstracts an ...