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- Guo, Shenyi, et al. Show all 8 Authors
- Journal of the American Chemical Society 2018 v.140 no.11 pp. 4028-4034
- cobalt; heat; ligands; macrocyclic compounds; oxidation; porphyrins; spectral analysis; zinc
- ... A new expanded porphyrin, hexadecaphyrin-(188.8.131.52.184.108.40.206.220.127.116.11.18.104.22.168), is reported. It was obtained via the condensation of a hexapyrrolic derivative prepared in turn from a bipyrrole dialdehyde and a stable quaterpyrrole precursor. This hexadecaphyrin contains eight direct α-pyrrole-to-α-pyrrole linkages in its structure. It supports the formation of bimetallic complexes of both zinc and cob ...