Jump to Main Content
- Kataria, Rhea, et al. Show all 8 Authors
- Journal of the American Chemical Society 2019 v.141 no.16 pp. 6740-6747
- acidity; encapsulation; enzymes; macrocyclization reactions; mathematical models; proteins
- ... The intrinsic structural complexity of proteins makes it hard to identify the contributions of each noncovalent interaction behind the remarkable rate accelerations of enzymes. Coulombic forces are evidently primary, but despite developments in artificial nanoreactor design, a picture of the extent to which these can contribute has not been forthcoming. Here we report on two supramolecular capsule ...