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- LiuThese authors contributed equally to this work., Binbin, et al. Show all 7 Authors
- Chemical communications 2019 v.55 no.33 pp. 4817-4820
- air; ambient temperature; bioactive compounds; chemical bonding; cleavage (chemistry); feedstocks; oxidants; oxidation; vanillin
- ... A general and selective iron-catalyzed allylic C–C(vinyl) σ-bond cleavage of allylarenes without the assistance of heteroatoms to give aryl aldehydes is reported. The unstrained carbon–carbon single bond cleavage reaction uses ambient air as the sole oxidant, proceeds efficiently at room temperature, and allows for exceptional functional-group tolerance, which addresses the long-standing challenge ...