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- Maheshwaran, Duraiyarasu, et al. Show all 4 Authors
- Journal of catalysis 2019 v.372 pp. 352-361
- allose; chemical structure; cleavage (chemistry); copper; enzymatic reactions; enzyme activity; enzymes; histidine; models; oxygen; p-nitrophenol; perchlorates; polysaccharides; pyridines; regioselectivity
- ... Lytic polysaccharide monooxygenases (LPMOs) are copper-containing monooxygenase and catalyzing the oxidative cleavage of recalcitrant polysaccharides using dioxygen. The copper(II) complexes [Cu(L1)(H2O)ClO4]ClO41, [L1 = 4-methyl-1-[(pyridin-2-yl-methyl)]-1,4-diazepane]; [Cu(L2)(H2O)ClO4]ClO42, [L2 = 4-methyl-1-[(2-(pyridine-2-yl)ethyl]-1,4-diazepane] and [Cu(L3)(H2O)ClO4]ClO43, [L3 = 1-(4-methoxy ...