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- Politidis, Christos, et al. Show all 5 Authors
- Macromolecules 2019 v.52 no.11 pp. 4185-4195
- adsorption; aluminum oxide; annealing; cooling; desorption; dielectric spectroscopy; differential scanning calorimetry; electric field; energy; geometry; glass; heat; molecular weight; nanopores; polymers; temperature
- ... The dynamics of a series of entangled cis-1,4-polyisoprenes located within self-ordered nanoporous alumina templates are studied as a function of the degree of confinement, 2Rg/d (Rg is the radius of gyration and d is the pore diameter) with dielectric spectroscopy and temperature-modulated differential scanning calorimetry. For the higher molecular weights, the segmental dynamics obtained on cool ...