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- Rivera, Edris, et al. Show all 5 Authors
- Journal of the American Chemical Society 2018 v.140 no.26 pp. 8192-8197
- free radicals; ketones; nanocrystals; photolysis
- ... Recent work has shown that diarylmethyl radicals generated by pulsed laser excitation in nanocrystalline (NC) suspensions of tetraarylacetones constitute a valuable probe for the detailed mechanistic analysis of the solid-state photodecarbonylation reaction. Using a combination of reaction quantum yields and laser flash photolysis in nanocrystalline suspensions of ketones with different substituen ...