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You searched for: Author "Yelena Sapozhnikova" Remove constraint Author: "Yelena Sapozhnikova"
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1. Assessing Chemical Migration from Plastic Food Packaging into Food Simulant by Gas and Liquid Chromatography with High-Resolution Mass Spectrometry

Author:
Yelena Sapozhnikova,   et al.   ; Taylor Raegyn B.;     Show all 2 Author
Source:
Journal of agricultural and food chemistry 2022 v.70 no.16 pp. 4805-4816
ISSN:
1520-5118
Subject:
food chemistry; food safety; liquid chromatography; mass spectrometry; meat
Abstract:
... Some components of plastic food packaging can migrate into food, and whereas migration studies of known components are required and relatively straightforward, identification of nonintentionally added substances (NIAS; unknowns) is challenging yet imperative to better characterizing food safety. To this aim, migration was investigated across 24 unique plastic food packaging products including plas ...
Handle:
10113/7756840
DOI:
10.1021/acs.jafc.2c00736
CHORUS:
10.1021/acs.jafc.2c00736

2. Validation of the QuEChERSER mega-method for the analysis of pesticides, veterinary drugs, and environmental contaminants in tilapia (Oreochromis Niloticus)

Author:
Yelena Sapozhnikova,   et al.   ; Sergio H. Monteiro; Steven J. Lehotay; Ederina Ninga; Graziela C.R. Moura Andrade; Alan R. Lightfield​;     Show all 6 Authors
Source:
Food additives & contaminants 2022 v.39 no.4 pp. 699-709
ISSN:
1944-0057
Subject:
Oreochromis niloticus; automation; chemical species; fish; food safety; freeze drying; gas chromatography; metabolites; muscles; pollution; polychlorinated biphenyls; robots; tandem mass spectrometry; ultra-performance liquid chromatography
Abstract:
... Diverse food safety programmes around the world are designed to help ensure production of safe food. To meet this need, the development and implementation of more efficient and effective analytical methods to monitor residues (pesticides and veterinary drugs) and contaminants in food is important. In this study, we report the validation results for a simple high-throughput mega-method for residual ...
Handle:
10113/7709667
DOI:
10.1080/19440049.2021.2020911

3. Analysis of pesticides, veterinary drugs, and environmental contaminants in goat and lamb by the QuEChERSER mega-method

Author:
Yelena Sapozhnikova,   et al.   ; Ederina Ninga; Steven J. Lehotay; Alan R. Lightfield; Gary D. Strahan; Sergio H. Monteiro;     Show all 6 Authors
Source:
Analytical methods 2022 v.14 no.28 pp. 2761-2770
ISSN:
1759-9679
Subject:
automation; chemical species; data quality; gas chromatography; goats; labor; liquids; metabolites; muscles; pollution; polychlorinated biphenyls; sheep; tandem mass spectrometry; trade
Abstract:
... Analysis of chemical residues in foods is a big challenge for developing countries due to lack of financial and professional resources needed to meet international quality standards for trade. However, the implementation of simple multiclass, multi-residue methods in monitoring programs can provide significant benefits to save cost, time, and labor. The aim of this project was to investigate the “ ...
DOI:
10.1039/d2ay00713d

4. Non-targeted analysis with liquid chromatography - high resolution mass spectrometry for the identification of food packaging migrants

Author:
Yelena Sapozhnikova,   et al.   ; Alberto Nuñez;     Show all 2 Author
Source:
Journal of chromatography 2022 v.1676 pp. 463215
ISSN:
0021-9673
Subject:
bisphenol A; bisphenol S; databases; liquid chromatography; liquid egg products; mass spectrometry; models; paper; pizza; risk; toxicology
Abstract:
... Potential contamination of food with chemicals migrating from food packaging is an important, yet under-investigated area of food safety. In this study, we examined chemicals migrating from common paper-based food packaging: pizza boxes and pizza box liners, butcher paper and liquid egg containers. Migration tests were conducted with a food simulant for 10 days, and migrated chemicals were identif ...
Handle:
10113/7796946
DOI:
10.1016/j.chroma.2022.463215
CHORUS:
10.1016/j.chroma.2022.463215

5. Non-targeted screening of chemicals migrating from paper-based food packaging by GC-Orbitrap mass spectrometry

Author:
Yelena Sapozhnikova
Source:
Talanta 2021 v.226 pp. 122120
ISSN:
0039-9140
Subject:
GRAS substances; alkanes; benzophenones; boxes (containers); dibutyl phthalate; fatty acid esters; food-packaging materials; gas chromatography-mass spectrometry; liquid egg products; meat; packaging materials migration; paper; pizza; risk management; siloxanes
Abstract:
... The aim of this study was to identify chemicals migrating from paper-based food packaging materials by GC-Orbitrap mass spectrometry (MS). Migration tests were conducted with samples of butcher paper, liquid egg containers, pizza boxes and pizza box liners. A new approach for an automated data processing of GC-Orbitrap EI data was developed and evaluated with Compound Discoverer™ software. A total ...
Handle:
10113/7241382
DOI:
10.1016/j.talanta.2021.122120
CHORUS:
10.1016/j.talanta.2021.122120

6. Semi-automated high-throughput method for residual analysis of 302 pesticides and environmental contaminants in catfish by fast low-pressure GC–MS/MS and UHPLC-MS/MS

Author:
Yelena Sapozhnikova,   et al.   ; Lijun Han;     Show all 2 Author
Source:
Food chemistry 2020 v.319 pp. 126592
ISSN:
0308-8146
Subject:
automation; catfish; chemical species; flame retardants; gas chromatography-mass spectrometry; lipophilicity; markets; metabolites; muscles; pesticides; pollution; polybrominated diphenyl ethers; polychlorinated biphenyls; polycyclic aromatic hydrocarbons; robots; tandem mass spectrometry; United States
Abstract:
... A fast, fit-for-purpose, high-throughput method was developed and validated for the analysis of 302 targeted contaminants in catfish muscle. Targeted contaminants included pesticides and metabolites with US regulatory levels, plus other lipophilic pesticides and environmental contaminants: PAHs, PCBs, PBDEs and other flame retardants. The sample preparation was based on QuEChERS extraction. The ex ...
DOI:
10.1016/j.foodchem.2020.126592

7. Screening of chemicals migrating from plastic food contact materials for oven and microwave applications by liquid and gas chromatography - Orbitrap mass spectrometry

Author:
Yelena Sapozhnikova,   et al.   ; Alberto Nuñez; John Johnston;     Show all 3 Authors
Source:
Journal of chromatography 2021 v.1651 pp. 462261
ISSN:
0021-9673
Subject:
electrospray ionization mass spectrometry; food contamination; gas chromatography; heat; ionization; isotope labeling; liquids; microwave ovens; oxidation
Abstract:
... Contamination of food with chemicals migrating from food contact materials (FCMs) is an important area of food safety. This study was aimed to investigate migration of chemicals from plastic FCMs used for microwave and conventional oven heating. Migration tests were conducted for samples of microwave trays, microwave oven bags, and oven bags. GC- and LC-Orbitrap mass spectrometry (MS) was used for ...
DOI:
10.1016/j.chroma.2021.462261
CHORUS:
10.1016/j.chroma.2021.462261

8. Evaluation of flow injection mass spectrometry approach for rapid screening of selected pesticides and mycotoxins in grain and animal feed samples

Author:
Yelena Sapozhnikova,   et al.   ; Paul Zomer; Arjen Gerssen; Alberto Nuñez; Hans G.J. Mol;     Show all 5 Authors
Source:
Food control 2020 v.116 pp. 107323
ISSN:
0956-7135
Subject:
chromatography; constitutional isomers; cyproconazole; detection limit; ethiofencarb; feed contamination; feeds; food analysis; food contamination; grains; instrumentation; ions; maximum residue limits; methiocarb; mycotoxins; pebulate; screening; spectral analysis; tandem mass spectrometry; uniconazole; vernolate
Abstract:
... A fast screening approach for simultaneous detection of twelve pesticides and seven mycotoxins in food and feed samples using flow injection (FI) mass spectrometry (MS) was developed and evaluated. Ten selected pesticides represented five pairs of structural isomers to challenge their MS differentiation without chromatographic separation. Samples of cereals/grains and animal feed were prepared usi ...
DOI:
10.1016/j.foodcont.2020.107323

9. Analysis and Occurrence of Organophosphate Esters in Meats and Fish Consumed in the United States

Author:
Yelena Sapozhnikova,   et al.   ; Lijun Han; Alberto Nuñez;     Show all 3 Authors
Source:
Journal of agricultural and food chemistry 2019 v.67 no.46 pp. 12652-12662
ISSN:
1520-5118
Subject:
acetonitrile; automation; beef; catfish; chickens; esters; flame retardants; flow injection analysis; gas chromatography-mass spectrometry; liquid chromatography; markets; maximum residue limits; muscle tissues; organophosphorus compounds; phosphates; plasticizers; pork; robots; salmon; tandem mass spectrometry; United States
Abstract:
... Organophosphate esters (OPEs) are chemicals extensively used as plasticizers and flame retardants in commercial and consumer products. In this study, we developed and validated a method for the analysis of 13 common OPEs in meat (chicken, pork, and beef) and fish (catfish and salmon) to study their occurrence in those foods in the United States. The method was based on QuEChERS extraction with ace ...
DOI:
10.1021/acs.jafc.9b01548

10. High-throughput analytical method for 265 pesticides and environmental contaminants in meats and poultry by fast low pressure gas chromatography and ultrahigh-performance liquid chromatography tandem mass spectrometry

Author:
Yelena Sapozhnikova
Source:
Journal of chromatography 2018 pp. -
ISSN:
0021-9673
Subject:
automation; cattle; chickens; flame retardants; gas chromatography; meat; monitoring; muscle tissues; muscles; pesticides; pollution; polybrominated diphenyl ethers; polychlorinated biphenyls; polycyclic aromatic hydrocarbons; robots; solid phase extraction; swine; tandem mass spectrometry; ultra-performance liquid chromatography; United States
Abstract:
... A high throughput method for simultaneous determination of 200 pesticides and 65 environmental contaminants: polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs), polybrominated diphenyl ethers (PBDEs) and other flame retardants, was developed and validated in cattle, swine and poultry muscle tissues. The method was based on sample preparation with QuEChERS extraction followed ...
DOI:
10.1016/j.chroma.2018.08.025

11. High-Throughput Mega-Method for the Analysis of Pesticides, Veterinary Drugs, and Environmental Contaminants by Ultra-High-Performance Liquid Chromatography–Tandem Mass Spectrometry and Robotic Mini-Solid-Phase Extraction Cleanup + Low-Pressure Gas Chromatography–Tandem Mass Spectrometry, Part 2: Catfish

Author:
Yelena Sapozhnikova,   et al.   ; Ederina Ninga; Steven J. Lehotay; Alan R. Lightfield; Sergio H. Monteiro;     Show all 5 Authors
Source:
Journal of agricultural and food chemistry 2020 v.69 no.4 pp. 1169-1174
ISSN:
1520-5118
Subject:
European Union; automation; catfish; chemical species; food chemistry; gas chromatography; liquid chromatography; metabolites; muscles; pollution; polychlorinated biphenyls; robots; tandem mass spectrometry
Abstract:
... The goal of this study was to develop and validate a new method for simultaneous determination of 106 veterinary drugs and 227 pesticides and their metabolites plus 16 polychlorinated biphenyls (PCBs) at and below their regulatory levels established for catfish muscle in the European Union and U.S.A. To do this, two different QuEChERS-based methods for veterinary drugs and pesticides and PCBs were ...
DOI:
10.1021/acs.jafc.0c00995

12. Use of a quality control approach to assess measurement uncertainty in the comparison of sample processing techniques in the analysis of pesticide residues in fruits and vegetables

Author:
Yelena Sapozhnikova,   et al.   ; Steven J. Lehotay; Lijun Han;     Show all 3 Authors
Source:
Analytical and bioanalytical chemistry 2018 v.410 no.22 pp. 5465-5479
ISSN:
1618-2642
Subject:
ambient temperature; apples; bananas; broccoli; celery; chopping; equipment; foods; freezing; fruits; gas chromatography; grapes; green beans; labor; monitoring; nitrogen; peaches; pesticide residues; portion size; potatoes; quality control; squashes; tandem mass spectrometry; ultra-performance liquid chromatography; uncertainty
Abstract:
... In routine monitoring of foods, reduction of analyzed test portion size generally leads to higher sample throughput, less labor, and lower costs of monitoring, but to meet analytical needs, the test portions still need to accurately represent the original bulk samples. With the intent to determine minimal fit-for-purpose sample size, analyses were conducted for up to 93 incurred and added pesticid ...
DOI:
10.1007/s00216-018-0905-1

13. High-Throughput Mega-Method for the Analysis of Pesticides, Veterinary Drugs, and Environmental Contaminants by Ultra-High-Performance Liquid Chromatography−Tandem Mass Spectrometry and Robotic Mini-Solid-Phase Extraction Cleanup + Low-Pressure Gas Chromatography−Tandem Mass Spectrometry, Part 1: Beef

Author:
Yelena Sapozhnikova,   et al.   ; Sergio H. Monteiro; Steven J. Lehotay; Ederina Ninga; Alan R. Lightfield;     Show all 5 Authors
Source:
Journal of agricultural and food chemistry 2020 v.69 no.4 pp. 1159-1168
ISSN:
1520-5118
Subject:
automation; beef; cattle; chemical pollutants; chemical species; cost effectiveness; food chemistry; freeze drying; gas chromatography; international trade; labor; liquid chromatography; metabolites; muscles; pollution; polychlorinated biphenyls; reference standards; risk assessment; robots; solid phase extraction; standard deviation; tandem mass spectrometry
Abstract:
... In this work, a new mega-method of sample preparation called “QuEChERSER” (more than QuEChERS) is being presented for the first time. Fast, efficient, and cost-effective analysis of chemical contaminants in meat is useful for international trade, domestic monitoring, risk assessment, and other purposes. The goal of this study was to develop and validate a simple high-throughput mega-method for res ...
DOI:
10.1021/acs.jafc.0c00710

14. Spatial and seasonal occurrence of semi-volatile organic compounds (SVOCs) in fish influenced by snowmelt and municipal effluent discharge

Author:
Yelena Sapozhnikova,   et al.   ; Amina Salamova; Samuel P. Haddad; S. Rebekah Burket; Michael Luers; Bryan W. Brooks;     Show all 6 Authors
Source:
Science of the total environment 2020 v.737 pp. 140222
ISSN:
0048-9697
Subject:
Cottus bairdii; Salmo trutta; biphenyl; chemical species; environment; fish; hexachlorobenzene; lipophilicity; metabolites; phosphates; polychlorinated biphenyls; snowmelt; streams; summer; volatile organic compounds; Utah
Abstract:
... In the present study we examined spatial and seasonal trends in the levels of a wide suite of semi-volatile organic compounds (SVOCs) in brown trout (Salmo trutta) and mottled sculpin (Cottus bairdii) in East Canyon Creek, Utah, USA, an effluent-dominated stream during summer months. Fish samples were collected from four sampling sites, including one reference site upstream, and three sites at inc ...
DOI:
10.1016/j.scitotenv.2020.140222

15. Residue Analysis of 60 Pesticides in Red Swamp Crayfish Using QuEChERS with High-Performance Liquid Chromatography–Tandem Mass Spectrometry

Author:
Yelena Sapozhnikova,   et al.   ; Shuangyu Song; Kechen Zhu; Lijun Han; Zihao Zhang; Wei Yao;     Show all 6 Authors
Source:
Journal of agricultural and food chemistry 2018 v.66 no.20 pp. 5031-5038
ISSN:
1520-5118
Subject:
Procambarus clarkii; acetonitrile; crayfish; difenoconazole; high performance liquid chromatography; markets; meat; multiresidue analysis; pesticide residues; phosphates; propamocarb; shrimp; sodium chloride; solid phase extraction; statistical analysis; tandem mass spectrometry; China
Abstract:
... In this study, a multi-residue analytical method using quick, easy, cheap, effective, rugged, and safe (QuEChERS) extraction and dispersive solid-phase extraction (d-SPE) cleanup, followed by high-performance liquid chromatography–tandem mass spectrometry (HPLC–MS/MS), was investigated for rapid determination of 60 pesticide residues in whole crayfish and crayfish meat. The final method used 10 mL ...
DOI:
10.1021/acs.jafc.7b05339

16. Evaluation of a new carbon/zirconia‐based sorbent for the cleanup of food extracts in multiclass analysis of pesticides and environmental contaminants

Author:
Yelena Sapozhnikova,   et al.   ; Lijun Han; Jessie Matarrita;     Show all 3 Authors
Source:
Journal of separation science 2016 v.39 no.23 pp. 4592-4602
ISSN:
1615-9306
Subject:
absorbance; avocados; chlorophyll; flame retardants; gas chromatography; kale; pesticides; pollution; polybrominated diphenyl ethers; polychlorinated biphenyls; polycyclic aromatic hydrocarbons; pork; salmon; solid phase extraction; sorbents; statistical analysis; tandem mass spectrometry
Abstract:
... A novel carbon/zirconia‐based material, Supelᵀᴹ QuE Verde, was evaluated in a filter‐vial dispersive solid‐phase extraction cleanup of pork, salmon, kale, and avocado extracts for the residual analysis of 65 pesticides and 52 environmental contaminants (flame retardants, polychlorinated biphenyls, polybrominated diphenyl ethers, and polycyclic aromatic hydrocarbons) using low‐pressure gas chromato ...
DOI:
10.1002/jssc.201600920

17. Automated Mini-Column Solid-Phase Extraction Cleanup for High-Throughput Analysis of Chemical Contaminants in Foods by Low-Pressure Gas Chromatography—Tandem Mass Spectrometry

Author:
Yelena Sapozhnikova,   et al.   ; Steven J. Lehotay; Lijun Han;     Show all 3 Authors
Source:
Chromatographia 2016 v.79 no.17-18 pp. 1113-1130
ISSN:
0009-5893
Subject:
adsorbents; apples; avocados; basil; carrots; chemical analysis; computer software; food matrix; gas chromatography; humans; kale; labor; olives; pesticides; pollution; pork; salmon; solid phase extraction; tandem mass spectrometry; wheat
Abstract:
... This study demonstrated the application of an automated high-throughput mini-cartridge solid-phase extraction (mini-SPE) cleanup for the rapid low-pressure gas chromatography—tandem mass spectrometry (LPGC-MS/MS) analysis of pesticides and environmental contaminants in QuEChERS extracts of foods. Cleanup efficiencies and breakthrough volumes using different mini-SPE sorbents were compared using av ...
DOI:
10.1007/s10337-016-3116-y
PubMed:
27616781
PubMed Central:
PMC4995235

18. Evaluation of Low-Pressure Gas Chromatography-Tandem Mass Spectrometry Method for the Analysis of > 140 Pesticides in Fish

Author:
Yelena Sapozhnikova
Source:
Journal of agricultural and food chemistry 2014 v.62 no.17 pp. 3684-3689
ISSN:
0021-8561
Subject:
heptachlor; chlorpyrifos; DDT (pesticide); solid phase extraction; lindane; detection limit; food analysis; dimethoate; pesticide residues; mirex; DDE (pesticide); DDD (pesticide); acetonitrile; hexachlorobenzene; markets; trifluralin; food contamination; trans-chlordane; tandem mass spectrometry; multiresidue analysis; catfish; gas chromatography
Abstract:
... A multiresidue method for the analysis of 143 pesticide residues in fish was developed and evaluated using fast, low-pressure gas chromatography/triple-quadrupole tandem mass spectrometry (LP-GC/MS-MS). The method was based on a QuEChERS (quick, easy, cheap, effective, rugged, safe) extraction with acetonitrile and dispersive solid-phase extraction (d-SPE) cleanup with zirconium-based sorbent. The ...
Handle:
10113/58819
DOI:
10.1021/jf404389e

19. At the Intersection of Urbanization, Water, and Food Security: Determination of Select Contaminants of Emerging Concern in Mussels and Oysters from Hong Kong

Author:
Yelena Sapozhnikova,   et al.   ; S. Rebekah Burket; J. S. Zheng; Shan Shan Chung; Bryan W. Brooks;     Show all 5 Authors
Source:
Journal of agricultural and food chemistry 2018 v.66 no.20 pp. 5009-5017
ISSN:
1520-5118
Subject:
Bivalvia; aquaculture; chemical residues; developing countries; drugs; flame retardants; food production; food security; foods; gas chromatography; infrastructure; isotope dilution technique; landfill leachates; liquid chromatography; municipal wastewater; mussels; net pens; oysters; pesticides; polybrominated diphenyl ethers; polychlorinated biphenyls; polycyclic aromatic hydrocarbons; product safety; risk; sewage; tandem mass spectrometry; urbanization; China
Abstract:
... Aquaculture, which is growing 3–5 times faster than terrestrial agriculture, will play an important role to meet future global food production needs. However, over 80% of global sewage production is returned to the environment untreated or poorly treated. In developing nations, these nontraditional waters of diverse quality are being recycled for aquaculture, yet chemical residues are differential ...
DOI:
10.1021/acs.jafc.7b05730
CHORUS:
10.1021/acs.jafc.7b05730

20. Use of an Efficient Measurement Uncertainty Approach To Compare Room Temperature and Cryogenic Sample Processing in the Analysis of Chemical Contaminants in Foods

Author:
Yelena Sapozhnikova,   et al.   ; Lijun Han; Steven J. Lehotay;     Show all 3 Authors
Source:
Journal of agricultural and food chemistry 2017 v.66 no.20 pp. 4986-4996
ISSN:
1520-5118
Subject:
ambient temperature; apples; automation; chemical pollutants; dry ice; gas chromatography; kale; liquids; nitrogen; portion size; quality control; salmon; solid phase extraction; tandem mass spectrometry; uncertainty
Abstract:
... In this study, analytical results were compared when using different approaches to bulk food sample comminution, consisting of a vertical chopper (Blixer) at room temperature and dry ice cryogenic conditions, followed by further subsample processing (20 g) using liquid nitrogen cryogenic conditions (cryomill). Analysis of the 43 targeted spiked and incurred contaminants in a food mixture consistin ...
DOI:
10.1021/acs.jafc.7b04359