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Removal of chloride from MSWI fly ash

Author:
Chen, Wei-Sheng, Chang, Fang-Chih, Shen, Yun-Hwei, Tsai, Min-Shing, Ko, Chun-Han
Source:
Journal of hazardous materials 2012 v.237-238 pp. 116-120
ISSN:
0304-3894
Subject:
air, calcium, calcium chloride, carbon dioxide, construction materials, drying, environmental impact, fly ash, landfills, neutralization, potassium chloride, recycling, roasting, sodium chloride, temperature, washing
Abstract:
The high levels of alkali chloride and soluble metal salts present in MSWI fly ash is worth noting for their impact on the environment. In addition, the recycling or reuse of fly ash has become an issue because of limited landfill space. The chloride content in fly ash limits its application as basis for construction materials. Water-soluble chlorides such as potassium chloride (KCl), sodium chloride (NaCl), and calcium chloride hydrate (CaCl₂·2H₂O) in fly ash are easily washed away. However, calcium chloride hydroxide (Ca(OH)Cl) might not be easy to leach away at room temperature. The roasting and washing-flushing processes were applied to remove chloride content in this study. Additionally, air and CO₂ were introduced into the washing process to neutralize the hazardous nature of chlorides. In comparison with the water flushing process, the roasting process is more efficient in reducing the process of solid–liquid separation and drying for the reuse of Cl-removed fly ash particles. In several roasting experiments, the removal of chloride content from fly ash at 1050°C for 3h showed the best results (83% chloride removal efficiency). At a solid to liquid ratio of 1:10 the water-flushing process can almost totally remove water-soluble chloride (97% chloride removal efficiency). Analyses of mineralogical change also prove the efficiency of the fly ash roasting and washing mechanisms for chloride removal.
Agid:
1015011