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Palladium catalyzed N-alkylation of amines with alcohols

Author:
Zhang, Yan, Qi, Xiujuan, Cui, Xinjiang, Shi, Feng, Deng, Youquan
Source:
Tetrahedron letters 2011 v.52 no.12 pp. 1334-1338
ISSN:
0040-4039
Subject:
X-ray diffraction, X-ray photoelectron spectroscopy, alcohols, amines, catalysts, chemical reactions, chemical structure, iron oxides, palladium
Abstract:
An iron oxide immobilized palladium catalyst was prepared for the N-alkylation of amines with alcohols under base and organic ligand free conditions. Applying the optimized reaction conditions, the coupling reactions of amines and alcohols with various structures could be realized with up to 99% isolated yields. The catalysts were studied by XRD, BET, and XPS and the mechanism was studied by DFT calculations.
Agid:
1097290