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Resembling a “natural formation pattern” of chlorinated dibenzo-p-dioxins by varying the experimental conditions of hydrothermal carbonization

Author:
Tirler, Werner, Basso, Albino
Source:
Chemosphere 2013 v.93 pp. 1464-1470
ISSN:
0045-6535
Subject:
anthropogenic activities, biomass, chlorination, clay, coal, dibenzofuran, food contamination, forest fires, hydrothermal carbonization, pollution, polychlorinated dibenzodioxins, sewage sludge, temperature, toxicity, United States
Abstract:
Until several years ago dioxins were considered as just an unwanted by product of anthropogenic activities and stigmatized as the symbol of man-made environmental pollution. Natural processes, such as forest fires, can emit dioxins, but compared to industrial processes, usually very low quantities are emitted. However after a case of food contamination occurred in the United States of America in 1996 caused by kaolinitic clay a discussion on the provenience started. Besides the relatively high concentration also an unusual PCDD/F distribution pattern was found in these ball clay samples. This specific pattern related to none of the known anthropogenic sources for these contaminants and, in relation to a supposed natural formation, later it was named “natural formation pattern”. Hydrothermal carbonization (HTC) can transform biomass within hours into a brown coal-like product which resembles naturally occurring coal formation. HTC can also transform an already present PCDD/F contamination in a way to obtain a “natural formation pattern” characterized by an unusual high ratio between 1,2,3,7,8,9-HxCDD and 1,2,3,6,7,8-HxCDD and the absence of almost all chlorinated dibenzofurans. By varying the experimental conditions of the HTC process applied to sewage sludge samples contaminated with PCDD/Fs from anthropogenic sources, beside the “natural formation pattern” at a temperatures of 255°C, a remarkable increase of the toxicity based on WHO–TEQ was observed.
Agid:
1122452