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A possible simplification of the Goss-modified Abraham solvation equation

Author:
van Noort, Paul C.M.
Source:
Chemosphere 2013 v.93 pp. 1742-1746
ISSN:
0045-6535
Subject:
chemistry, equations, organic compounds, solvents, statistical analysis, water
Abstract:
Abraham solvation equations find widespread use in environmental chemistry and pharmaco-chemistry. Recently Goss proposed a modified Abraham solvation equation. For various partitioning processes, the present study investigates the consequences for the fit when the Abraham solvation parameter V is left out of this modified solvation equation. For air-organic solvent partition, the Abraham solvation parameter V can be omitted from the Goss-modified Abraham solvation equation without any loss of statistical quality. For air–water partitioning, organic biphasic system partitioning, as well as water-organic solvent partitioning, omitting the V parameter from the Goss-modified Abraham solvation equation leads to only a small deterioration of statistic quality.
Agid:
1122462