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Arsenic Removal from Groundwater by Goethite Impregnated Calcium Alginate Beads

Author:
Basu, H., Singhal, R. K., Pimple, M. V., Reddy, A. V. R.
Source:
Water, air, and soil pollution 2015 v.226 no.2 pp. 2251
ISSN:
0049-6979
Subject:
adsorbents, arsenic, calcium alginate, goethite, groundwater, models, pH, sodium alginate, sorption, sorption isotherms
Abstract:
In the present work, goethite (α-FeO(OH)) impregnated calcium alginate (Cal-Alg-Goe) beads were used to sorb the arsenic from groundwater without disturbing its physicochemical characteristics. Beads were formed by dropwise addition of homogenized mixer of goethite and 4 % sodium alginate solution in 0.2 M CaCl₂solution. Charge, size, and morphology of sorbents were characterized by using various techniques. The results of batch sorption experiments suggest that Cal-Alg-Goe beads are very effective for removal of arsenic in the pH range 3.0 to 7.5, and sorption was more than 95 % in the concentration range of 10–10,000 ng mL⁻¹. Beads were successfully tested for groundwater samples collected from areas having elevated levels of arsenic. Equilibrium sorption follows Langmuir isotherm model, and the maximum arsenic uptake calculated was 30.44 mg g⁻¹. The sorption kinetics could be explained by pseudo-first-order model, and the time needed for equilibrium was 24 h.
Agid:
1206695