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Turkish Tombul Hazelnut (Corylus avellana L.). 2. Lipid Characteristics and Oxidative Stability

Author:
Alasalvar, Cesarettin, Shahidi, Fereidoon, Ohshima, Toshiaki, Wanasundara, Udaya, Yurttas, Hasan C., Liyanapathirana, Chandrika M., Rodrigues, Fabiana B.
Source:
Journal of agricultural and food chemistry 2003 v.51 no.13 pp. 3797-3805
ISSN:
0021-8561
Subject:
Corylus avellana, alpha-tocopherol, beta-sitosterol, fatty acid composition, hazelnut oil, hazelnuts, lipid content, lipid peroxidation, oleic acid, oxidative stability, peroxide value, stearic acid, storage time, thiobarbituric acid-reactive substances
Abstract:
The quality of crude hazelnut oil extracted from Tombul (Round) hazelnut, grown in the Giresun province of Turkey, was determined by measuring lipid classes, fatty acids, and fat soluble bioactives (tocopherols and phytosterols). Oxygen uptake, peroxide value, thiobarbituric acid reactive substances, and α-tocopherol levels of stripped and crude hazelnut oils in bulk and oil-in-water (o/w) emulsion systems were also evaluated as indices of lipid oxidation over a 21 day storage period at 60 °C in the dark. The total lipid content of Tombul hazelnut was 61.2%, of which 98.8% were nonpolar and 1.2% polar constituents. Triacylglycerols were the major nonpolar lipid class and contributed nearly 100% to the total amount. Phosphatidylcholine, phosphatidylethanolamine, and phosphatidylinositol were the most abundant polar lipids, respectively. Sixteen fatty acids were identified, among which oleic acid contributed 82.7% to the total, followed by linoleic, palmitic, and stearic acids. Unsaturated fatty acids accounted for 92.2% of the total fatty acids present. Among oil soluble bioactives, α-tocopherol (38.2 mg/100 g) and β-sitosterol (105.5 mg/100 g) were predominant in hazelnut oil and comprised 88 and 93% of the total tocopherols and phytosterols present, respectively. The results also showed that both stripped and crude hazelnut oils were more stable in terms of lipid oxidation in the bulk oil as compared to those in an o/w emulsion.
Agid:
312537