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2-Acetylfuran-3-Glucopyranoside as a Novel Marker for the Detection of Honey Adulterated with Rice Syrup

Author:
Xue, Xiaofeng, Wang, Qiang, Li, Yi, Wu, Liming, Chen, Lanzhen, Zhao, Jing, Liu, Fengmao
Source:
Journal of agricultural and food chemistry 2013 v.61 no.31 pp. 7488-7493
ISSN:
1520-5118
Subject:
adulterated products, high performance liquid chromatography, honey, markets, nuclear magnetic resonance spectroscopy, rice, syrups
Abstract:
The determination of honey authenticity is of importance to ensure its quality and safety. There is an urgent need of effective methods to detect adulterated honey. A simple, rapid, and effective HPLC–DAD method was developed to detect honey adulteration by rice syrup, using a characteristic compound from rice syrup, which is presently difficult to detect by current analytical methods. The characteristic compound was identified as 2-acetylfuran-3-glucopyranoside (AFGP) by MS and NMR. Based on HPLC analyses, the average concentration of AFGP was 92 ± 60 mg/kg in rice syrup. However, AFGP was not detected in any of the natural honey samples, so it could be used as a marker for the detection of honey adulteration by rice syrup. The developed method enabled a rapid detection of honey samples adulterated with 10% rice syrup. Using the developed method, 16 out of 186 honey samples from some markets were found to be adulterated with rice syrup.
Agid:
322195