PubAg

Main content area

Metall-Bor-Verbindungen, XII / Metal Boron Compounds, XII : Diphenylboryl- und Dibromboryl-stannane / Diphenylboryl and Dibromoboryl Stannanes

Author:
Nöth, Heinrich, Schäfer, Helwig, Schmid, Günter
Source:
Zeitschrift für Naturforschung 2014 v.26 no.6 pp. 497-503
ISSN:
0932-0776
Subject:
boron compounds, chemical reactions, chemical structure
Abstract:
Diphenylboryl stannanes [ (C₆H₅) ₂B]₄ ₋ ₙSn(CH₃) ₙ (n = 0, 1, 2, 3) are produced from methyl chloro stannanes and (diphos)₂Co[B(C₆H₅) ₂] ₂. However, no dibromoboryl stannanes (Br₂B)₄ ₋ ₙSn(CH₃)ₙ could be isolated in a similar reaction using (diphos) ₂Co(BBr₂) ₂ but they are stabilized by addition of diphos yielding the complexes (Br₂B)₄ ₋ ₙSn(CH₃)ₙ · m diphos which contain B — P bonds.
Agid:
5213749