PubAg

Main content area

Notizen: Gezielte Synthese von Sulfinato-O̲- und -S̲-Komplexen einiger Übergangsmetalle, XVI1 Sulfinato-S̲-Komplexe von Palladium(II) mit schwachen Donorliganden. : Directed Synthesis of Sulfinato-O̲- and -S̲-Complexes of Some Transition Metals, XVI1 Sulfinato-S̲ Complexes of Palladium(II) with Weak Donor Ligands

Author:
Lorenz, Ingo-Peter, Lindner, Ekkehard, Reuther, Wolfgang
Source:
Zeitschrift für Naturforschung 2014 v.31 no.10 pp. 1425-1426
ISSN:
0932-0776
Subject:
acetonitrile, ligands, palladium, sodium
Abstract:
The complexes Na[(RS(O)₂)₂PdClL] (L = CH₃CN (2), (CH₃)₂CO (3), THF (4)), stable in solid state, are obtained by substitution of H₂O by weak donor ligands from Na[(RS(O)₂)₂PdCl(OH₂)] (1). Their special reactivity in solution is shown by the ready substitution of all ligands, RSO₂⁻ included. The IR spectra are discussed.
Agid:
5214772