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Notizen: Azide und Nitrile cyclischer λ5-Phosphazene / Azides and Nitriles of Cyclic λ5-Phosphazenes

Author:
Roesky, Herbert W., Banek, Manfred
Source:
Zeitschrift für Naturforschung 2014 v.34 no.5 pp. 752-754
ISSN:
0932-0776
Subject:
chlorides, nitriles, potassium cyanide, sodium azide
Abstract:
The kinetically stable triazatriphosphorinyl and tetraazatetra-phosphorocinyl azides 3 and 4 are prepared from the corresponding chlorides 1, 2 with sodium azide. 3 and 4 react with phosphanes to yield the λ⁵ -diphosphazenes 5a-d. By the reaction of 1 or 2 with KCN the nitriles 6 and 7 are formed. -The new compounds are characterized on the basis of IR and mass spectra.
Agid:
5215923