PubAg

Main content area

Tl4Ge4Se10, ein Thallium(1)selenogermanat mit adamantananalogem Anion [Ge4Se10]4- / Tl4Ge4Se10, a Thallium(I) Selenogermanate with the Adamantane-Like Anion [Ge4Se10]4-

Author:
Eulenberger, Günther
Source:
Zeitschrift für Naturforschung 2014 v.36 no.4 pp. 521-523
ISSN:
0932-0776
Subject:
anions, cations, crystal structure, thallium
Abstract:
Tl₄Ge₄Se₁₀ crystallizes in space group C2/c with a = 15.602(6), b = 15.549(5), c = 9.052(3) Å, β - 107.10(3)° and Z = 4. The compound was prepared by fusion of a stoichiometric mixture of Tl₂Se and GeSe₂. The crystal structure is characterized by adamantane-like anions [Ge₄Se₁₀]⁴⁻ and Tl⁺ cations. Tl₄Ge₄Se₁₀ is iso-structural with Tl₄Ge₄S₁₀ [1].
Agid:
5216492