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Enamine als Zwischenprodukte der Simon-Awe-Komplexe / Enamines as Intermediates of Simon-Awe Complexes

Author:
Wiegrebe, Wolfgang, Vilbig, Margit
Source:
Zeitschrift für Naturforschung 2014 v.37 no.4 pp. 490-493
ISSN:
0932-0776
Subject:
acetaldehyde, acetone, cyclohexanones, enamines, piperidines
Abstract:
Enamines from acetaldehyde, propionaldehyde and cyclohexanone produce coloured complexes with disodium-pentakis-(cyano-C)-nitrosylferrate(2) more rapidly than the carbonyl components together with piperidine, so indicating enamine intermediates. - The Legal complexes from acetaldehyde and acetone are protonated to the corresponding Simon-Awe complexes.
Agid:
5216742