PubAg

Main content area

Synthese und Struktur von N2S3Cl+SbCI6 - / Synthesis and Structure of N2S3Cl+ SbCl6-

Author:
Isenberg, Wilhelm, Homsy, Nayla K., Anhaus, Jens, Roesky, Herbert W., Sheldrick, George M.
Source:
Zeitschrift für Naturforschung 2014 v.38 no.7 pp. 808-810
ISSN:
0932-0776
Subject:
anions, cations, chlorination, chlorine, crystals
Abstract:
N₂S₃Cl+ SbCl₆- was prepared by chlorination of N₄S₄ · SbCls₅ with elemental chlorine. The crystals are monoclinic, P2₁/c, with a = 1492.4(4), b = 1233.6(2), c = 1437.5(4) pm, β = 91.40(2)°, and R = 0.059 for 3663 observed reflections. There are two independent cations and anions in the asymmetric symmetric unit. The appreciable interionic interaction results in a high density of ρ = 2.642 g · cm -3 (calcd).
Agid:
5217087