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Exploring the effect of cellulose nanowhiskers isolated from oil palm biomass on polylactic acid properties

Author:
Haafiz, M.K. Mohamad, Hassan, Azman, Khalil, H.P.S. Abdul, Fazita, M.R. Nurul, Islam, Md. Saiful, Inuwa, I.M., Marliana, M.M, Hussin, M. Hazwan
Source:
International journal of biological macromolecules 2016 v.85 pp. 370-378
ISSN:
0141-8130
Subject:
Elaeis guineensis, atomic force microscopy, biomass, cellulose, hydrolysis, modulus of elasticity, nanocomposites, nanocrystals, polylactic acid, resins, scanning electron microscopy, sulfuric acid, tensile strength, thermal stability, transmission electron microscopy
Abstract:
In this work, polylactic acid (PLA) reinforced cellulose nanowhiskers (CNW) were prepared through solution casting technique. The CNW was first isolated from oil palm empty fruit bunch microcrystalline cellulose (OPEFB-MCC) by using 64% H2SO4 and was designated as CNW-S. The optical microscopy revealed that the large particle of OPEFB-MCC has been broken down by the hydrolysis treatment. The atomic force microscopy confirmed that the CNW-S obtained is in nanoscale dimension and appeared in individual rod-like character. The produced CNW-S was then incorporated with PLA at 1, 3, and 5 parts per hundred (phr) resins for the PLA-CNW-S nanocomposite production. The synthesized nanocomposites were then characterized by a mean of tensile properties and thermal stability. Interestingly to note that incorporating of 3phr/CNW-S in PLA improved the tensile strength by 61%. Also, CNW-S loading showed a positive impact on the Young’s modulus of PLA. The elongation at break (Eb) of nanocomposites, however, decreased with the addition of CNW-S. Field emission scanning electron microscopy and transmission electron microscopy revealed that the CNW-S dispersed well in PLA at lower filler loading before it started to agglomerate at higher CNW-S loading (5phr). The DSC analysis of the nanocomposites obtained showed that Tg,Tcc and Tm values of PLA were improved with CNW-S loading. The TGA analysis however, revealed that incopreated CNW-S in PLA effect the thermal stability (T10,T50 and Tmax) of nanocomposite, where it decrease linearly with CNW-S loading.
Agid:
5293901