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High Solubilities for Methane, Ethane, Ethylene, and Propane in Trimethyloctylphosphonium Bis(2,4,4-trimethylpentyl) Phosphinate ([P8111][TMPP])

Author:
Liu, Xiangyang, Ruiz, Elia, Afzal, Waheed, Ferro, Víctor, Palomar, José, Prausnitz, John M.
Source:
Industrial & Engineering Chemistry Research 2014 v.53 no.1 pp. 363-368
ISSN:
1520-5045
Subject:
cations, engineering, ethane, ethylene, ionic liquids, methane, prediction, propane, solubility
Abstract:
Solubilities are reported for methane, ethane, ethylene, and propane in trimethyloctylphosphonium bis(2,4,4-trimethylpentyl) phosphinate [P8111][TMPP] from 299 to 323 K up to 4 MPa. Consistent with prediction of COSMO-RS, [P8111][TMPP] shows large solubilities for all four hydrocarbons. Contrary to solubility data in conventional ionic liquids, in [P8111][TMPP] the solubility for ethane is higher than that for ethylene. When compared with solubilities in other similar phosphonium-based ionic liquids, the cation has only a small influence on the solubilities of small hydrocarbons. Ionic liquid [P8111][TMPP] may be useful for storage or separation of small hydrocarbons.
Agid:
5376545