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A Multifunctional Organic–Inorganic Hybrid Structure Based on MnIII–Porphyrin and Polyoxometalate as a Highly Effective Dye Scavenger and Heterogenous Catalyst
- Zou, Chao, Zhang, Zhijuan, Xu, Xuan, Gong, Qihan, Li, Jing, Wu, Chuan-De
- Journal of the American Chemical Society 2012 v.134 no.1 pp. 87-90
- catalysts, chemical structure, dyes, oxidation, porphyrins
- A two-step synthesis strategy has led to a unique layered polyoxometalate–Mnᴵᴵᴵ–metalloporphyrin-based hybrid material. The hybrid solid demonstrates remarkable capability for scavenging of dyes and for heterogeneous selective oxidation of alkylbenzenes with excellent product yields and 100% selectivity.