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Copper-Catalyzed Synthesis of Mixed Alkyl Aryl Phosphonates

Author:
Fañanás-Mastral, Martín, Feringa, Ben L.
Source:
Journal of the American Chemical Society 2014 v.136 no.28 pp. 9894-9897
ISSN:
1520-5126
Subject:
catalysts, chemical reactions, copper, oxygen, phosphonates, salts
Abstract:
Copper-catalysis allows the direct oxygen-arylation of dialkyl phosphonates with diaryliodonium salts. This novel methodology proceeds with a wide range of phosphonates and phosphoramidates under mild conditions and gives straightforward access to valuable mixed alkyl aryl phosphonates in very good yields and near perfect selectivity.
Agid:
5391904