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Agarsenone, a Cadinane Sesquiterpenoid from Commiphora erythraea

Author:
Santoro, Stefano, Superchi, Stefano, Messina, Federica, Santoro, Ernesto, Rosati, Ornelio, Santi, Claudio, Marcotullio, M. Carla
Source:
Journal of natural products 2013 v.76 no.7 pp. 1254-1259
ISSN:
1520-6025
Subject:
Commiphora, circular dichroism spectroscopy, nuclear magnetic resonance spectroscopy, sesquiterpenoids, spectral analysis
Abstract:
Agarsenone (1), a new cadinane sesquiterpenoid, was isolated from the resin of Commiphora erythraea. The structures of 1 and its decomposition products agarsenolides (2a and 2b) and myrrhone (3) were established by extensive NMR spectroscopic analysis. The absolute configuration of 3 and the relative and absolute configurations of 1 were assigned by comparison of experimental and calculated optical rotatory dispersion and electronic circular dichroism spectra.
Agid:
5494059