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Catalyst-Free Approach to Construct C–C Bond Initiated by N–O Bond Cleavage under Thermal Conditions
- Li, Dan-Dan, Li, Zhong-Yuan, Wang, Guan-Wu
- Journal of organic chemistry 2015 v.80 no.1 pp. 190-195
- additives, catalysts, chemical bonding, cleavage (chemistry), organic chemistry, sustainable technology
- An unexpected and novel approach to construct the sp² C–sp³ C bond has been developed via N–O bond cleavage without any external catalysts or additives. It is a very simple, efficient, and environmentally friendly method and will be a very attractive radical process toward new C–C bond formation.