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Streaming potential method for characterizing the overlapping of diffuse layers of the electrical double layers between oppositely charged particles

Author:
Li, Zhong-yi, Li, Jiu-yu, Xu, Ren-kou, Hong, Zhi-neng, Liu, Zhao-dong
Source:
Colloids and Surfaces A: Physicochemical and Engineering Aspects 2015 v.478 pp. 22-29
ISSN:
0927-7757
Subject:
aluminum, aluminum oxide, coatings, colloids, electrolytes, gibbsite, ionic strength, iron, quartz, soil, zeta potential
Abstract:
Interaction of the electrical double layers (EDLs) between negatively charged quartz grains and positively charged iron (Fe)/aluminum (Al) oxide colloids was investigated in this work by comparing the difference in zeta potentials between the single quartz in electrolyte and quartz with Fe/Al oxide suspensions. The Fe/Al oxides used were α-Fe2O3, amorphous Fe hydroxide, gibbsite and amorphous Al hydroxide. The zeta potential of quartz was measured using a self-made streaming potential apparatus. Our results indicated that the overlapping degree of diffuse layers of the EDLs between quartz and Fe/Al oxides increased with increased concentration of Fe/Al oxides and decreased with the decrease in negative surface charge on quartz due to ferric coating. The overlapping degree of diffuse layers of the EDLs between quartz and Fe/Al oxides decreased with increased ionic strength due to the decreased thickness of the diffuse layers. The results should provide a useful reference for using the streaming potential method to investigate the effect of the colloidal transport process on the properties of bulk soil in situ.
Agid:
5528782