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Influence of Electric Fields on the Electron Transport in Donor–Acceptor Polymers

Author:
Förster, Anja, Günther, Florian, Gemming, Sibylle, Seifert, Gotthard
Source:
The Journal of Physical Chemistry C 2017 v.121 no.7 pp. 3714-3723
ISSN:
1932-7455
Subject:
electric field, electron transfer, energy, physical chemistry, polymers, transistors
Abstract:
The influence of an electric field on different properties of the donor–acceptor polymer diketo-pyrrolo-pyrrole bithiophene thienothiophene (DPPT-TT) that are essential for the charge transport process is studied. The main focus is on whether the transport in DPPT-TT-based organic transistors can be tuned by electric fields in the gate direction. The considered electric fields are in the range 10⁸–10¹⁰ V m–¹. We show that strong electric fields (∼10⁹ V m–¹) which are parallel to the polymer backbone can influence the reorganization energy in a Markus-type approach. Weaker electric fields parallel to the polymer backbone result in minimal changes to the reorganization energy. The coupling element of DPPT-TT shows a pronounced affinity to be influenced by electric fields in the charge transport direction independent of the field strength.
Agid:
5678909