PubAg

Main content area

AlCl3 catalyzed oxa-Diels-Alder reaction of aromatic aldehydes with simple dienes

Author:
Jian, Wujun, Qian, Bo, Bao, Hongli, Li, Daliang
Source:
Tetrahedron 2017 v.73 pp. 4039-4044
ISSN:
0040-4020
Subject:
Lewis acids, aldehydes, aluminum chloride, chemical reactions, chemical structure, nitrogen dioxide
Abstract:
A highly regioselective and diastereoselective oxa-Diels-Alder reaction catalyzed by AlCl3 has been developed. This reaction is efficient and characterized by good functional group compatibility, F, Cl, CN, NO2, OMe and thiophenyl groups are tolerated. A Lewis acid catalyzed concerted cycloaddition mechanism is proposed based on the results.
Agid:
5705545