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Removal of heavy metal ions by magnetic chitosan nanoparticles prepared continuously via high-gravity reactive precipitation method
- Fan, Hong-Lei, Zhou, Shao-Feng, Jiao, Wei-Zhou, Qi, Gui-Sheng, Liu, You-Zhi
- Carbohydrate polymers 2017 v.174 pp. 1192-1200
- adsorbents, adsorption, aqueous solutions, cadmium, chitosan, heavy metals, iron oxides, lead, metal ions, nanoparticles, wastewater treatment
- This study aimed to provide a continuous method for the preparation of magnetic Fe3O4/Chitosan nanoparticles (Fe3O4/CS NPs) that can be applied to efficient removal of heavy metal ions from aqueous solution. Using a novel impinging stream-rotating packed bed, the continuous preparation of Fe3O4/CS NPs reached a theoretical production rate of 3.43kg/h. The as-prepared Fe3O4/CS NPs were quasi-spherical with average diameter of about 18nm and saturation magnetization of 33.5emu/g. Owing to the strong metal chelating ability of chitosan, the Fe3O4/CS NPs exhibited better adsorption capacity and faster adsorption rates for Pb(II) and Cd(II) than those of pure Fe3O4. The maximum adsorption capacities of Fe3O4/CS NPs for Pb(II) and Cd(II) were 79.24 and 36.42mgg−1, respectively. In addition, the Fe3O4/CS NPs shown excellent reusability after five adsorption-desorption cycles. All the above results provided a potential method for continuously preparing recyclable adsorbent with a wide prospect of application in wastewater treatment.