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Ethanol-Processable, Highly Crystalline Conjugated Polymers for Eco-Friendly Fabrication of Organic Transistors and Solar Cells

Author:
Nguyen, Thanh Luan, Lee, Changyeon, Kim, Hyoeun, Kim, Youngwoong, Lee, Wonho, Oh, Joon Hak, Kim, Bumjoon J., Woo, Han Young
Source:
Macromolecules 2017 v.50 no.11 pp. 4415-4424
ISSN:
1520-5835
Subject:
absorption, chemical structure, chlorobenzene, ethanol, fullerene, guidelines, polymers, solar cells, solvents, transistors
Abstract:
We report eco- and human-friendly fabrication of organic field-effect transistors (OFETs) and polymer solar cells (PSCs) using only ethanol as a processing solvent at ambient condition, in stark contrast to that involving the use of halogenated and/or aromatic solvents. New ethanol-processable electroactive materials, p-type polymer (PPDT2FBT-A) and n-type bis-adduct fullerene acceptor (Bis-C₆₀-A) are designed rationally by incorporation of oligoethylene glycol (OEG) side-chains. By ethanol processing, PPDT2FBT-A shows a broad light absorption in the range of 300–700 nm and highly crystalline interchain ordering with out-of-plane interlamellar scattering up to (400) with strong π–π stacking. As a result, the ethanol-processed PPDT2FBT-A OFETs yield high charge-carrier mobilities up to 1.0 × 10–² cm² V–¹ s–¹, which is the highest value reported to date from alcohol-processed devices. Importantly, the ethanol-processed PPDT2FBT-A OFET outperformed that processed using typical processing solvent, chlorobenzene (CB), with ∼10-fold enhancement in hole mobility, because the highly edge-on oriented packing of PPDT2FBT-A was produced by ethanol-process. Also, for the first time, significant photovoltaic performance was achieved for the ethanol-processed device of PPDT2FBT-A and Bis-C₆₀-A due to the formation of an interpenetrating nanofibrillar morphology of highly crystalline PPDT2FBT-A polymers. The relationships between molecular structure, nanoscale morphology and electronic properties within ethanol-processed OFETs and PSCs were elucidated by comparing to typical CB-processed devices. These comparisons provide important guidelines for the design of new ethanol/water-soluble active layer materials and their use in the development of green solvent-processed efficient OFETs and PSCs.
Agid:
5783017