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Total Synthesis of Aspercyclides A and B via Intramolecular Oxidative Diaryl Ether Formation

Author:
Yoshino, Tatsuya, Sato, Itaru, Hirama, Masahiro
Source:
Organic letters 2012 v.14 no.16 pp. 4290-4292
ISSN:
1523-7052
Subject:
chemical bonding, chemical reactions, chemical structure, organic compounds, regioselectivity
Abstract:
A highly efficient total synthesis of the 11-membered cyclic aspercyclides A (1) and B (2) has been achieved by chemo- and regioselective intramolecular oxidative C–O bond formation from differently substituted diphenols.
Agid:
5784231