PubAg

Main content area

Studies toward the Synthesis of Spirolide C: Exploration into the Formation of the 23-Membered All-Carbon Macrocyclic Framework

Author:
Stivala, Craig E., Gu, Zhenhua, Smith, Lindsay L., Zakarian, Armen
Source:
Organic letters 2012 v.14 no.3 pp. 804-807
ISSN:
1523-7052
Subject:
aldehydes, chemical reactions, chemical structure
Abstract:
The synthesis of two complex subunits en route to spirolide C is described. A key alkyllithium addition to an aldehyde joins the fragments, which are advanced in order to investigate a ring-closing metathesis to form the 23-membered all-carbon macrocyclic framework.
Agid:
5784860