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Regioselective Enzymatic Carboxylation of Phenols and Hydroxystyrene Derivatives

Author:
Wuensch, Christiane, Glueck, Silvia M., Gross, Johannes, Koszelewski, Dominik, Schober, Markus, Faber, Kurt
Source:
Organic letters 2012 v.14 no.8 pp. 1974-1977
ISSN:
1523-7052
Subject:
benzoic acid, carboxylation, chemical structure, phenols, regioselectivity, styrene
Abstract:
The enzymatic carboxylation of phenol and styrene derivatives using (de)carboxylases in carbonate buffer proceeded in a highly regioselective fashion: Benzoic acid (de)carboxylases selectively formed o-hydroxybenzoic acid derivatives, phenolic acid (de)carboxylases selectively acted at the β-carbon atom of styrenes forming (E)-cinnamic acids.
Agid:
5785152