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MeOTf-Induced Carboannulation of Isothiocyanates and Aryl Alkynes with CS Bond Cleavage: Access to Indenones

Author:
Zhao, Peng, Liu, Yu, Xi, Chanjuan
Source:
Organic letters 2015 v.17 no.17 pp. 4388-4391
ISSN:
1523-7052
Subject:
alkynes, chemical reactions, cleavage (chemistry), isothiocyanates, moieties
Abstract:
MeOTf-induced carboannulation of alkyl isothiocyanates and aryl alkynes for the synthesis of indenones in good yields under metal-free conditions with CS bond cleavage is described. The thioalkoxy group at the 3-position of the indenone can also be converted into other functional groups, such as phenyl, methylsulfonyl, amino, and ethoxy groups.
Agid:
5789548