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A Catalyst-Free Synthesis of Phosphinic Amides Using O-Benzoylhydroxylamines

Author:
Zhu, Rui, Pan, Chongqing, Gu, Zhenhua
Source:
Organic letters 2015 v.17 no.23 pp. 5862-5865
ISSN:
1523-7052
Subject:
air, amides, chemical reactions, chemical structure, oxides, phosphine, potassium carbonate
Abstract:
A practical approach for the synthesis of phosphinic amides via the coupling of secondary phosphine oxides (SPOs) with O-benzoylhydroxylamines has been reported. Simply heating the mixture of SPOs and O-benzoylhydroxylamines in the presence of K₂CO₃ gave the phosphinic amides in moderate to excellent yields under an open air system. This method provides a practical and catalyst-free method for the synthesis of various synthetically valuable phosphinic amides.
Agid:
5789980