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Mercury isotope signatures of seawater discharged from a coal-fired power plant equipped with a seawater flue gas desulfurization system

Author:
Lin, Haiying, Peng, Jingji, Yuan, Dongxing, Lu, Bingyan, Lin, Kunning, Huang, Shuyuan
Source:
Environmental pollution 2016 v.214 pp. 822-830
ISSN:
0269-7491
Subject:
carbon, coal, flue gas, flue gas desulfurization, isotope labeling, isotopes, mercury, minerals, mixing, pollutants, power plants, seawater, statistical models, sulfides, sulfur dioxide, China
Abstract:
Seawater flue gas desulfurization (SFGD) systems are commonly used to remove acidic SO2 from the flue gas with alkaline seawater in many coastal coal-fired power plants in China. However, large amount of mercury (Hg) originated from coal is also transferred into seawater during the desulfurization (De-SO2) process. This research investigated Hg isotopes in seawater discharged from a coastal plant equipped with a SFGD system for the first time. Suspended particles of inorganic minerals, carbon residuals and sulfides are enriched in heavy Hg isotopes during the De-SO2 process. δ202Hg of particulate mercury (PHg) gradually decreased from −0.30‰ to −1.53‰ in study sea area as the distance from the point of discharge increased. The results revealed that physical mixing of contaminated De-SO2 seawater and uncontaminated fresh seawater caused a change in isotopic composition of PHg isotopes in the discharging area; and suggested that both De-SO2 seawater and local background contributed to PHg. The impacted sea area predicted with isotopic tracing technique was much larger than that resulted from a simple comparison of pollutant concentration. It was the first attempt to apply mercury isotopic composition signatures with two-component mixing model to trace the mercury pollution and its influence in seawater. The results could be beneficial to the coal-fired plants with SFGD systems to assess and control Hg pollution in sea area.
Agid:
5830412