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Stereoselective Synthesis of Pear Ester

Author:
Shakhmaev, R.N., Sunagatullina, A.Sh., Akimova, D.A., Zorin, V.V.
Source:
Chemistry of natural compounds 2017 v.53 no.6 pp. 1017-1019
ISSN:
0009-3130
Subject:
cross-coupling reactions, esters, oxidation, pears, stereoselective synthesis
Abstract:
A simple two-step synthesis of ethyl-(2E,4Z)-deca-2,4-dienoate based on Fe-catalyzed cross-coupling of ethyl-(2E,4Z)-5-chloropenta-2,4-dienoate, which was obtained via one-pot oxidation and olefination of readily available (2Z)-3-chloroprop-2-en-1-ol by n-pentylmagnesiumbromide, was developed.
Agid:
5867247