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Research on the thermal behavior of novel heat resistance explosive 5,5′-bis(2,4,6-trinitrophenyl)-2,2′-bi(1,3,4-oxadiazole)

Author:
Zhou, Jing, Ding, Li, Bi, Fuqiang, Wang, Bozhou, Zhang, Junlin
Source:
Journal of analytical and applied pyrolysis 2017
ISSN:
0165-2370
Subject:
Fourier transform infrared spectroscopy, differential scanning calorimetry, energy, heat tolerance, moieties, pyrolysis, reaction kinetics, thermal stability, thermogravimetry
Abstract:
5,5′-bis(2,4,6-trinitrophenyl)-2,2′-bi(1,3,4-oxadiazole) (TKX-55) was synthesized through an oxidation-chloridization-condensation-cyclization sequence. Thermal decomposition behavior and non-isothermal decomposition reaction kinetics of TKX-55 were investigated by the differential scanning calorimetry and thermogravimetric analysis (DSC-TG) methods The research of decomposition mechanism of the molecule was further carried out through in-situ FTIR spectroscopy technologies. The experiment results showed that the enlarged conjugated system has a marked effect on the thermal stability and the picryl moiety is much more stable than the 1,3,4-oxadiazole moiety during the heat-up process, indicating that the decomposition process is mostly likely to initiate from the ring-opening reaction of 1,3,4-oxadiazole moiety which is supported by the computational scanning result of potential energy surface.
Agid:
5869824