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Facile synthesis of cuboid Ni-MOF for high-performance supercapacitors

Author:
Gao, Shuwen, Sui, Yanwei, Wei, Fuxiang, Qi, Jiqiu, Meng, Qingkun, He, Yezeng
Source:
Journal of materials science 2018 v.53 no.9 pp. 6807-6818
ISSN:
0022-2461
Subject:
capacitance, carbon, coordination compounds, electrodes, electrolytes, hot water treatment, nickel, porous media, potassium hydroxide, specific energy
Abstract:
Metal–organic frameworks (MOF) used directly in supercapacitors have attracted much attention for their special porous structure and potential high performance. Here, the Ni-MOF is fabricated by one-step facile hydrothermal method with a modification of mixed solution with DMF and water instead of pure DMF. After characterization, the Ni-MOF exhibits loosely stacked layer-cuboid structure with abundant mesoporous, which is beneficial for the charge transfer and ion transport for supercapacitors. In the three-electrode system, this Ni-MOF serving as working electrode shows remarkable specific capacitance of 804 Fg⁻¹ at 1 Ag⁻¹, excellent rate capacitance of 534 Fg⁻¹ at 10 Ag⁻¹, and with 302 Fg⁻¹ retention after 5000 cycles, when measured in 2 M KOH electrolyte solution. To make a further research into the practical utility of the Ni-MOF, the Ni-MOF//AC asymmetrical supercapacitor device is assembled with the Ni-MOF and active carbon acted as positive and negative electrode materials, respectively. This device exhibits high specific energy of 31.5 Wh kg⁻¹, at specific power of 800 W kg⁻¹. All these results demonstrate that this Ni-MOF is a kind of promising electrode material for high-performance supercapacitors.
Agid:
5902501