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Paper miniaturization via periodate oxidation of cellulose

Author:
Strong, E.Brandon, Kirschbaum, C.Ward, Martinez, AndresW., Martinez, NathanielW.
Source:
Cellulose 2018 v.25 no.6 pp. 3211-3217
ISSN:
0969-0239
Subject:
cellulose, oxidation, paper, surface area
Abstract:
Cellulose-based paper is a versatile material with a diverse array of applications. While paper is not commonly thought of as a material that shrinks, here we present a method for miniaturizing paper via periodate oxidation. Chromatography paper was exposed to varying concentrations of periodate (0.1–0.5 M) over a 96-h period. Following optimization of miniaturization parameters, fourteen different types of paper were miniaturized and reductions in surface area ranging from 60 to 80% were observed. All cellulose paper types, but not cellulose-derivatives, displayed successful miniaturization. Results were highly tunable dependent upon periodate concentration and reaction time. Potential applications of the technique are discussed, including its use as a microfabrication method.
Agid:
5946437