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As(V) and Sb(V) co-adsorption onto ferrihydrite: synergistic effect of Sb(V) on As(V) under competitive conditions

Author:
Wu, Debo, Sun, Sheng-Peng, He, Minghe, Wu, Zhangxiong, Xiao, Jie, Chen, XiaoDong, Wu, WinstonDuo
Source:
Environmental science and pollution research international 2018 v.25 no.15 pp. 14585-14594
ISSN:
0944-1344
Subject:
X-ray photoelectron spectroscopy, adsorption, antimony, arsenic, chemical bonding, ferrihydrite, ionic strength, oxygen, pH, synergism
Abstract:
Competitive adsorption of As(V) and Sb(V) at environmentally relevant concentrations onto ferrihydrite was investigated. Batch experiments and XPS analyses confirmed that in a binary system, the presence of Sb(V) exhibited a slight synergistic effect on As(V) adsorption. XPS analyses showed that As(V) and Sb(V) adsorption led to obvious diminishment of Fe–O–Fe and Fe–O–H bonds respectively. At pH of 9, a more significant decrease of Fe–O–Fe was observed in the binary system than that in a single system, indicating that As(V) displayed an even stronger interaction with lattice oxygen atoms under competitive conditions. Basically, ionic strength demonstrated a negligible or positive influence on As(V) and Sb(V) adsorption in binary system. Study of adsorption sequence also indicated that the presence of Sb(V) showed a promotion effect on As(V) adsorption at neutral pHs. Considering that co-contamination of As and Sb in waters has been of great concern throughout the world, our findings contributed to a better understanding of their distribution, mobility, and fate in environment.
Agid:
5952060