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Cationization of lignocellulosic fibers with betaine in deep eutectic solvent: Facile route to charge stabilized cellulose and wood nanofibers

Author:
Sirviö, Juho Antti
Source:
Carbohydrate polymers 2018 v.198 pp. 34-40
ISSN:
0144-8617
Subject:
betaine, cationization, cellulose, cellulose microfibrils, chlorides, lignin, lignocellulose, mechanical pulp, nanofibers, solvents, wood
Abstract:
In this study, a deep eutectic solvent (DES [based on triethylmethylammonium chloride (TEMA) and imidazole]) was used as a reaction medium for cationization of cellulose fibers with trimethylglycine (betaine) hydrochloride in the presence of p-Toluenesulfonyl (tosyl) chloride. Cellulose betaine ester with a cationic charge up to 1.95 mmol/g was obtained at mild reaction conditions (four hours at 80 °C). The reaction was further demonstrated in the fabrication of cationic cellulose nanofibers (CCNFs) by a mild mechanical disintegration of cationized cellulose. In addition to CCNFs, cationic wood nanofibers (CWNFs) were produced directly from groundwood pulp (GWP) with a high lignin content (27 w%). Individualized CCNFs and CWNFs had a fiber diameter of 4.7 ± 2.0 and 3.6 ± 1.3 nm, respectively, whereas some larger fiber aggregates (diameter below 200 nm) were also observed, especially in the case of CWNFs.
Agid:
5980785