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Hydrogen permeation and surface properties of PdAu and PdAgAu membranes in the presence of CO, CO2 and H2S

Author:
Dalla Fontana, Agustina, Sirini, Noelí, Cornaglia, Laura M., Tarditi, Ana M.
Source:
Journal of membrane science 2018 v.563 pp. 351-359
ISSN:
0376-7388
Subject:
X-ray photoelectron spectroscopy, alloys, artificial membranes, carbon dioxide, carbon monoxide, hydrogen, hydrogen sulfide, silver, temperature
Abstract:
Using the electroless deposition technique with different deposition sequences, it was possible to obtain a single phase PdAgAu ternary alloy after treatment at 773 K during 7 days. Despite the order of deposition, the samples exhibited similar hydrogen permeation flux at the same temperature and pressure. In the presence of CO, the PdAgAu ternary alloy membranes showed a lower inhibition on the hydrogen permeance compared with the binary PdAu alloy at 623 and 673 K. On the contrary, under CO2 containing streams, the ternary alloy showed a higher inhibition with a complete hydrogen recovery after removing CO2 from the stream. When H2S was introduced in the 13% CO2/13% Ar/74% H2 stream, a higher permeance decrease was observed on both the PdAu and PdAgAu alloy membranes. After removal of H2S, a hydrogen recovery of 60% and 76% was measured for the PdAu and PdAgAu membranes, respectively. Pd surface segregation was observed on the Pd82Ag15Au3–873 K-5 d and the Pd78Au6Ag16–773 K-7 d samples upon exposure to CO containing streams. Instead, silver surface segregation was observed by XPS after exposing the PdAgAu ternary alloy to CO2 containing streams.
Agid:
5985123