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Arylation of perfluoroalkyl vinyl sulfoxides via the Heck reaction
- Sokolenko, Liubov V., Yagupolskii, Yurii L., Vlasenko, Yurii G., Babichenko, Liudmila N., Lipetskij, Volodimir O., Anselmi, Elsa, Magnier, Emmanuel
- Tetrahedron letters 2015 v.56 no.10 pp. 1259-1262
- arylation, byproducts, catalysts, moieties, organoiodine compounds, palladium, perfluorocarbons
- Heck reactions of perfluoroalkyl vinyl sulfoxides with aryl iodides are studied and palladium(II) acetate is shown to be the most convenient catalyst for this process. New E-1-aryl-2-perfluoroalkylsulfinylethylenes are synthesized. In all cases, by-products without a perfluoroalkylsulfinyl group are formed.