PubAg

Main content area

Arylation of perfluoroalkyl vinyl sulfoxides via the Heck reaction

Author:
Sokolenko, Liubov V., Yagupolskii, Yurii L., Vlasenko, Yurii G., Babichenko, Liudmila N., Lipetskij, Volodimir O., Anselmi, Elsa, Magnier, Emmanuel
Source:
Tetrahedron letters 2015 v.56 no.10 pp. 1259-1262
ISSN:
0040-4039
Subject:
arylation, byproducts, catalysts, moieties, organoiodine compounds, palladium, perfluorocarbons
Abstract:
Heck reactions of perfluoroalkyl vinyl sulfoxides with aryl iodides are studied and palladium(II) acetate is shown to be the most convenient catalyst for this process. New E-1-aryl-2-perfluoroalkylsulfinylethylenes are synthesized. In all cases, by-products without a perfluoroalkylsulfinyl group are formed.
Agid:
6025086