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Fluorescent Cyanine Dye J-Aggregates in the Fluorous Phase

Author:
Cao, Wei, Sletten, Ellen M.
Source:
Journal of the American Chemical Society 2018 v.140 no.8 pp. 2727-2730
ISSN:
1520-5126
Subject:
fluorescence, fluorescent dyes, photostability, solvents
Abstract:
We present a perfluorocarbon-hydrocarbon amphiphilic cyanine dye that J-aggregates in fluorous solvent. J-Aggregation is a special type of fluorophore aggregation, affording enhanced photophysical properties. Cyanine dyes are excellent J-aggregators in water but, until now, cyanine J-aggregates have not been translated to nonaqueous media. The fluorous phase J-aggregate displays enhanced photostability and processability compared to analogous aqueous aggregates.
Agid:
6038498