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Ni-Catalyzed Site-Selective Dicarboxylation of 1,3-Dienes with CO2

Author:
Tortajada, Andreu, Ninokata, Ryo, Martin, Ruben
Source:
Journal of the American Chemical Society 2018 v.140 no.6 pp. 2050-2053
ISSN:
1520-5126
Subject:
carbon dioxide, feedstocks, isoprene, regioselectivity
Abstract:
A site-selective catalytic incorporation of multiple CO₂ molecules into 1,3-dienes en route to adipic acids is described. This protocol is characterized by its mild conditions, excellent chemo- and regioselectivity and ease of execution under CO₂ (1 atm), including the use of bulk butadiene and/or isoprene feedstocks.
Agid:
6038678