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Oxidative Dephosphorylation of Benzylic Phosphonates with Dioxygen Generating Symmetrical trans-Stilbenes

Author:
Huang, Tianzeng, Chen, Tieqiao, Han, Li-Biao
Source:
Journal of organic chemistry 2018 v.83 no.5 pp. 2959-2965
ISSN:
1520-6904
Subject:
dephosphorylation, moieties, organic chemistry, oxygen, phosphonates
Abstract:
Under a dioxygen atmosphere, benzylphosphonates and related phosphoryl compounds can readily produce the corresponding trans-stilbenes in high yields with high selectivity upon treatment with bases. Various functional groups were tolerable under the reaction conditions.
Agid:
6046912