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Transition-Metal-Free C–P Bond Formation via Decarboxylative Phosphorylation of Cinnamic Acids with P(O)H Compounds

Author:
Liu, Lixin, Zhou, Dan, Dong, Jianyu, Zhou, Yongbo, Yin, Shuang-Feng, Han, Li-Biao
Source:
Journal of organic chemistry 2018 v.83 no.7 pp. 4190-4196
ISSN:
1520-6904
Subject:
chemical bonding, chemical structure, cinnamic acid, decarboxylation, organic chemistry, oxides, phosphorylation
Abstract:
A novel, transition-metal-free phosphorylation of cinnamic acids with P(O)H compounds has been developed via radical-promoted decarboxylation under mild conditions. This method provides simple, efficient, and versatile access to valuable (E)-alkenylphosphine oxides in satisfactory yields with a wide variety of substrates.
Agid:
6047081